Beyond Gaussian Statistics in Polymer Melts: Statistical Masking of Persistent Local Constraints
This study reveals that the recovery of Gaussian statistics in long polymer chains is not caused by the disappearance of persistent local structural heterogeneities, but rather by a statistical masking effect where the accumulation of random conformational segments obscures the non-Gaussian signatures of enduring aligned domains, a process quantified by a -Gaussian distribution and a decreasing Tsallis entropy ratio.