Effect of cations on van der Waals interactions between particles in aqueous alkali nitrate electrolytes
By extending Lifshitz theory with a dielectric response model based on electronic structure calculations, this study reveals that increasing concentrations of sodium, potassium, and rubidium nitrates unexpectedly enhance the van der Waals interactions (Hamaker constants) of rutile, boehmite, and alumina nanoparticles, whereas cesium nitrate has negligible effect, challenging prevailing assumptions about electrolyte impacts on colloidal stability.
Micah P. Prange, Jaehun Chun, Gregory K. Schenter, Elias Nakouzi, Yihui Wei, Aurora E. Clark, Kevin M. Rosso, Carolyn I. Pearce2026-06-04🔬 cond-mat