Is the Eyring Plot Misleading? A Case for Arrhenius Analysis of Activation Parameters
This paper challenges the prevailing view that the Eyring plot is more fundamental than the Arrhenius plot by demonstrating that harmonic models yield exact linearity in Arrhenius representations, that the Eyring formulation's quantum appearance stems from normalization conventions rather than physics, and that an alternative Arrhenius-based framework offers more physically relevant and interpretable activation parameters.