📄 chemistry

Design, Construction and Performance Evaluation of a Low-Cost Pilot-Scale Semi-Batch Pyrolysis Plant for Converting Polystyrene and Low-Density Polyethylene Waste into Fuel Oil

This study demonstrates the technical feasibility of a low-cost, locally fabricated pilot-scale semi-batch pyrolysis plant for converting polystyrene and low-density polyethylene waste into fuel oil, reporting specific operational parameters, yield differences, and fuel properties while identifying key areas for process improvement.

Miracle Ajoku, Ebube Daniel Ezeokolie, Benjamin Chiebonam Nweke, Muyideen Alaaya Taofeeq, Azubuike Progress Ojinika, Mat (…)2026-10-19
📄 chemistry

Enhancement in the yield and properties of cellulose nanocrystals by two- batch addition of ammonium persulfate

This study demonstrates that a two-batch addition of ammonium persulfate during cellulose nanocrystal isolation significantly enhances yield, aspect ratio, and thermal stability while reducing polydispersity, ultimately leading to superior mechanical properties in polyvinyl alcohol/CNC composite films compared to the traditional single-batch method.

Zhangyun Chen, Zhongyuan Xie, Hua Jiang2026-10-19
📄 chemistry

Chalcogenide perovskites BaTi(OS)3 with band gap in the optimal Shockley-Queisser range

This study demonstrates that synthesizing chalcogenide perovskite BaTi(O₁₋ₓSₓ)₃ via CS₂ sulfidation of BaTiO₃ at elevated temperatures induces a tetragonal-to-hexagonal structural transition and reduces the band gap to the optimal Shockley-Queisser range of 1.47 eV.

Fátima Lizbeth González Gregorio, Roberto Goméz Rosales, Abraham Isaac Oliva Nuñez, Emmanuel de la O Cuevas, Angel Garcí (…)2026-10-19
📄 chemistry

Cyclotron production of [68Ga]GaCl3 using solid target and its clinical adaptation through automated purification and GMP-grade production of [68Ga]Ga-DOTATATE

This study presents a scalable, GMP-compliant workflow for the cyclotron-based production of [68Ga]GaCl3 via solid-target irradiation and its automated conversion into [68Ga]Ga-DOTATATE, offering a self-reliant solution to overcome the supply limitations of generator-based gallium-68 for neuroendocrine tumor imaging.

Waqas Rafique, Surrendra Nakka, Yellareddy Yerram, Hussein Salim Aldossari, Amr Mohammed Ibrahim Hendy, Subhani Okarvi2026-10-18
📄 chemistry

Cold-chamber die-casting manufacturing and characterization of aluminum matrix syntactic foams

This study demonstrates the technical feasibility of cold-chamber die casting for the industrial-scale production of aluminum matrix syntactic foams using pre-fixed Al₂O₃ hollow spheres, achieving excellent filler integrity and competitive mechanical properties such as a compressive strength of 151.1 MPa and specific energy absorption of 25.7 J/g.

Péter SZALVA, Ibolya KARDOS, Dóra KÁROLY, Anna SZIJÁRTÓ, Tamás BUBONYI, Tamás RICK, Melissza ZSOLDOS, Alexandra KEMÉNY (…)2026-10-16
📄 chemistry

Development of Schiff Base Chemosensors for Visual Detection of Cu²⁺, Fe²⁺, and Pb²⁺ Ions: Experimental Validation and Theoretical Support

This study reports the synthesis and characterization of thiocarbohydrazide-based Schiff base ligands that serve as efficient, selective, and visually responsive chemosensors for Cu²⁺, Fe²⁺, and Pb²⁺ ions, with their 1:1 binding stoichiometry and bidentate coordination mechanism validated through both experimental colorimetric analysis and Conceptual Density Functional Theory calculations.

Swathi Harithas, Chaitanya Lakshmi G2026-10-16
📄 chemistry

Composition-structure-property relationships in thermally evaporated ZnS thin films and Ag/n-ZnS/FTO Schottky barrier diodes

This study demonstrates that thermally evaporated, near-stoichiometric ZnS thin films with tunable structural and optical properties exhibit high n-type conductivity and visible transparency, enabling the fabrication of high-performance Ag/n-ZnS/FTO Schottky barrier diodes suitable for photovoltaic and electronic applications.

Dimple Singh, Zahoor Ahmed, Zakir Hussain, Naresh Padha2026-10-16
📄 chemistry

GC- MS Profiling of Storage-Related Changes in Phyto Compounds and Lipidome of Murraya koenigii Leaves

This study demonstrates that refrigerated storage significantly degrades the phytochemical and lipid profiles of *Murraya koenigii* leaves, leading to reduced therapeutic and aromatic compounds, altered lipid composition, and potential contamination, thereby compromising their overall quality and safety.

Sathiya Aravindan Venkatesan, Kannan Periyan, Madhan Kumar Kannan, Sunil Suriya Murugaiah, Balaji Ganesan, Kannan Raju (…)2026-10-16
📄 chemistry

Achieving simultaneous flame retardancy and mechanical reinforcement in PLA via PAPP/La 2 O 3 synergistic catalysis and uniaxial pre-stretching

This study demonstrates that combining a PAPP/nano-La₂O₃ synergistic flame-retardant system with uniaxial pre-stretching post-treatment effectively transforms brittle polylactic acid (PLA) into a ductile material with superior fire safety (UL-94 V-0 rating) and significantly enhanced mechanical properties, offering a promising solution for high-performance bioplastic applications.

Ruilu Yang, Lijing Han, Tianyi Ma, Qiuhong Zhou, Junjia Bian, Yan Zhao, Hongwei Pan, Huiliang Zhang, Jingwei Li, Jianguo (…)2026-10-16