1711 papers
This paper presents a programmable deconstruction–reconstruction strategy that enables the divergent skeletal editing of pyridines into structurally diverse multisubstituted benzenes through controlled single-atom and atom-pair transformations, offering a versatile platform for late-stage functionalization of pharmaceuticals and bioactive molecules.
This paper presents a comprehensive theoretical framework for analyzing sequential double-regenerative enzymatic mechanisms in protein-film voltammetry, revealing distinct electrochemical fingerprints that enable the quantitative extraction of kinetic parameters and the mechanistic interpretation of redox protein behaviors.
This study establishes a robust analytical framework for characterizing complex bauxite residue by combining closed-vessel microwave-assisted multi-acid digestion with suppressed ion chromatography and helium-collision cell ICP-MS to accurately quantify both trace rare earth elements and soluble inorganic anions while effectively managing matrix interferences and fluoride hazards.
This study successfully isolated and characterized a linoleic-linolenic acid mixture, spinasterol, and lupeol from *Strobilanthes dyeriana* leaf extract using a combination of chromatographic and spectroscopic techniques, confirming the plant's phytochemical composition.
This study demonstrates that in confined polymer–ionic liquid materials, competing ordering tendencies can be resolved through frustration-mediated structural-state selection, where the suppression of long-range order into a predominantly amorphous state (as seen in pMBA–FSI) uniquely optimizes ionic conductivity by overcoming the traditional trade-off between structural order and molecular mobility.
This study demonstrates that treating soybean hull agro-waste with sulfuric acid followed by pyrolysis at temperatures up to 800°C effectively transforms its morphology and chemical composition, yielding a value-added material with promising characteristics for use as a renewable reinforcement in sustainable composite applications.
Although formaldehyde crosslinked *Sargassum* seaweed demonstrates rapid and strong affinity for removing trace copper from urban runoff, the process is significantly compromised by the destabilization of its surface ionic layer, leading to the excessive release of organic matter and high concentrations of potassium, sodium, calcium, and magnesium ions.
MolTabReco is a multi-stage framework that integrates table-coordinate grounding, vision-language models, and optical chemical structure recognition to accurately recover molecular structures from chemical literature tables as canonical SMILES strings, significantly outperforming existing methods that fail to convert structural depictions into computable data.
This study presents a novel Ni-doped γ-Al₂O₃ multifunctional catalyst featuring frustrated Lewis pairs and spinel interlayers that achieves high-efficiency low-temperature CO₂ methanation through synergistic acid-base interactions and strong metal-support stabilization of ultra-fine Ni nanoparticles.
This study demonstrates that a domestic-scale hybrid electrocoagulation-anodic oxidation reactor, optimized with a triple-electrode configuration, effectively treats household greywater with high removal efficiencies for turbidity and organic pollutants while significantly reducing energy consumption, thereby validating its potential for decentralized water reuse applications.