Photoredox/Copper Synergistic Catalysis: One-Step Modular Assembly of Sulfonimidamides from Aryl Diazonium Salts, Tr-NSO, and Amines
This paper reports the first photoredox/copper dual-catalyzed, redox-neutral one-step assembly of arylsulfonimidamides from aryl diazonium salts, Tr-NSO, and amines via concurrent C–S and S–N bond formation, offering a highly efficient and general strategy that circumvents competing side reactions and unlocks the reactivity of sulfonimidoyl radicals for constructing diverse S(VI)-containing scaffolds.