📄 chemistry

Selective Hydrogenolysis of Glycerol to 1,2-Propanediol over a NaBH4-Reduced Cu–Pd/TiO2 Catalyst

A NaBH4-reduced Cu–Pd/TiO2 catalyst was demonstrated to be superior to monometallic counterparts for the selective hydrogenolysis of dilute aqueous glycerol to 1,2-propanediol, achieving a 63.38% conversion under optimized reaction conditions while highlighting the influence of operating variables on product distribution.

Ado Ibrahim Yargaya, Shamsudeen Mikail, Suleiman Yusif Sule, Abbas Abdurrahman Yusuf, Manniru Abdullahi Ali, Ahmad Muham (…)2026-10-07
📄 chemistry

Congo red photocatalytic degradation on the copper nanoparticles deposited on carriers

This study demonstrates that copper nanoparticles (4.5 wt.%) synthesized on gamma alumina and natural clinoptilolite zeolite both effectively degrade Congo Red dye via photocatalysis, with the alumina-supported catalyst exhibiting superior performance attributed to its enhanced mesoporosity and a higher proportion of smaller 2 nm nanoparticles.

Lyubov Kazymyrivna Patrylak, Yakovenko A.V., Hutsul K.R., Pertko O.P., Kamenskyh D.S.2026-10-07
📄 chemistry

Multielement absorption-edge complementarity in liquid metal amalgams enables Pb-free, lightweight, and flexible X-ray shielding

This study introduces a flexible, lead-free liquid metal amalgam composed of a Ga-In-Sn matrix and up to 27 dispersed metallic elements that eliminates weak absorption windows across the 1–100 keV range, achieving 39% higher shielding efficiency than lead while maintaining performance under extreme deformation.

Wei Rao, Yunlong Bai, Li Liu, Zhaosen Yuan, Jun Su, Tangzhen Guan, Zhen Zhang, Yujing Liu, Minghui Guo, Jianbo Tang2026-10-06
📄 chemistry

Green Synthesis and Characterisation of Iron Oxide Nanoparticles Using Rice Husk and Orange Peel Extracts and Residue Templates (RHOPTNPs) for the Adsorptive Removal of Ciprofloxacin and Ibuprofen from Aqueous Solution

This study demonstrates the successful green synthesis of iron oxide nanoparticles using rice husk and orange peel extracts and residues (RHOPTNPs), which effectively remove ciprofloxacin and ibuprofen from aqueous solutions through a spontaneous, chemisorption-driven monolayer adsorption mechanism.

Habib Isa ADAMU, Abdulrahman Abdulmumin Gbenga, Muhammad-Najeeb Oluwafemi Yusuf2026-10-06
📄 chemistry

Calcium-Induced Loss of Antibacterial Activity in Catechol-Based Phytochemicals: Implications for Biomaterial Design

This study demonstrates that calcium ions significantly impair the antibacterial efficacy and stability of catechol-containing phytochemicals through chelation, highlighting the critical need to select non-catechol alternatives or account for these interactions when designing calcium-rich bone and dental biomaterials.

Nora ABDELLAOUI, Cedric BOSSARD, Nicolas CHARBONNEL, Roman AGUAY, Edouard JALLOT, Aela LE BRUN, Philippe BOUCHARD, Jonat (…)2026-10-06
📄 chemistry

Electrochemical Post-Treatment of Constructed Wetland Effluent for Enhanced Ketoprofen Removal and Toxicity Reduction

This study demonstrates that coupling a vertical flow constructed wetland with photoelectro-Fenton treatment effectively removes over 99% of ketoprofen from real wastewater, significantly reduces toxicity, and offers a cost-effective, sustainable strategy for advanced wastewater polishing.

Isabel Maximo Corrêa Alcantara, Thalita Ferreira Silva, Priscila Sabioni Cavalheri, Emmanuel da Silva Côgo Miguel, Anton (…)2026-10-06
📄 chemistry

Mechanism of Mold-Induced Degradation of Silicone Rubber Under Microgravity in Space Environment

This study utilizes in-orbit experiments on the China Space Station to demonstrate that microgravity significantly inhibits the growth and metabolic activity of *Aspergillus brasiliensis* on silicone rubber, resulting in reduced organic acid secretion and lower material degradation compared to ground controls, thereby providing critical insights for spacecraft material protection.

Yao Tan, Yiding Zhou, Chao Cheng, Nana Chen, Xiaowen Song, Tong Tong, Lin Lu, Shuyuan Zhang, Wende Zhang, Kui Xiao2026-10-06
📄 chemistry

Cation-intercalated copper azide breaks the safety–energy trade-off in primary explosives

This study introduces a cation-intercalation strategy to synthesize a new class of primary explosives, (Et4N)2[Cu8(N3)18], which overcomes the traditional safety–energy trade-off of copper azide by achieving superior electrostatic safety and initiation efficiency compared to the industry-standard lead azide.

Wei-Xiong Zhang, Yun-Fan Yan, Ming-Yu Guo, Qian-You Wang, Meng Cui, Xu-Yang wang, Liu Liu, Shuai-Qi Ning, Si-Yuan Hao, Y (…)2026-10-06
📄 chemistry

Structure-based optimization of LRH-0003 derivatives targeting SARS-CoV-2 Mac1: discovery of L-5-A with improved binding affinity and favorable drug-like properties

Through structure-based optimization of the lead compound LRH-0003 targeting the SARS-CoV-2 Mac1 domain, researchers discovered the novel derivative L-5-A, which exhibits significantly improved binding affinity driven by specific hydrogen bonding and hydrophobic interactions, alongside favorable drug-like properties suitable for further antiviral development.

ZHIXUAN LI2026-10-06
📄 chemistry

Synergistic Corrosion Inhibition of Carbon Steel in Borewell Water by Beetroot Extract and Zn²⁺: Gravimetric, Electrochemical and Surface-Morphological Investigations

This study demonstrates that an aqueous beetroot extract, which alone shows limited or negative inhibition, synergistically enhances corrosion protection for carbon steel in borewell water when combined with Zn²⁺, achieving an 84% inhibition efficiency through the formation of a protective anodic film confirmed by gravimetric, electrochemical, and surface-morphological analyses.

C. S.A. Raj, Susai Rajendran2026-10-06