Atomic-Layer-Deposited ZnF2 on Al Enabling in situ NaF/Na–Zn Interphase for Robust Anode-Free Sodium Batteries
This study presents an atomic-layer-deposited ZnF₂-coated aluminum current collector that electrochemically transforms into a synergistic NaF/Na–Zn interphase, enabling highly reversible sodium plating and achieving exceptional cycling stability in high-energy-density anode-free sodium batteries.