📄 chemistry

Valorization of Wastepaper Ash and Waste Ceramic Powder as Supplementary Cementitious Materials in Cement Mortar Production

This study demonstrates that incorporating a 15% mixture of wastepaper ash and waste ceramic powder as a supplementary cementitious material significantly enhances the mechanical, durability, and microstructural properties of cement mortar, offering a viable and sustainable solution for partial cement replacement.

Reyot Alemu Kebede, Sofonias Alemayehu Desta, Bahiru Bewket Mitikie, Wallelgn Mulugeta2026-07-14
📄 chemistry

An aptamer-controlled Mn-Au oxidase-mimicking nanozyme for smartphone-assisted colorimetric detection of mercury ions

This study presents a smartphone-assisted colorimetric platform for detecting mercury ions using a Mn-Au hybrid nanozyme whose oxidase-mimicking activity is reversibly controlled by an aptamer that desorbs upon specific Hg²⁺ binding, enabling sensitive and on-site environmental monitoring.

Chen Ma, Yida Zhang, Shuai Mu, Yuan Zhang, Shuoyun Wei, Quanfang Li, Shufang Ren2026-07-14
📄 chemistry

Geometry and the Emergence of Molecular Order in Early Life: A General Phenomenological Framework for Disorder-Limited Surface Symmetry Breaking, Applied to Prebiotic Homochirality

This paper proposes a general phenomenological framework demonstrating that geometric order, quantified by a new surface uniformity parameter, acts as an independent control variable that allows prebiotic systems to maintain useful chiral symmetry breaking despite substantial microscopic disorder, with gradual rather than threshold-like tolerance confirmed through modeling and falsifiable experimental predictions.

Leon Sandler2026-07-14
📄 chemistry

A machine learning-based method for adulteration detection in white rice vinegar using different non-targeted spectroscopy

This study demonstrates that Fourier transform infrared (FTIR) spectroscopy coupled with machine learning outperforms near-infrared and fluorescence techniques in detecting synthetic acetic acid adulteration in white rice vinegar, while highlighting the critical necessity of tailoring chemometric models to specific vinegar brands due to significant variability in optimal preprocessing and feature selection strategies.

Xin Xu, Fengzhong Wang, Dongqi Guo, Bo Wang, Yatao Huang, Bei Fan, Ziyang Wu, Long Li2026-07-14
📄 chemistry

Development of a simple and affordable TLC-UV/Vis spectrophotometric method for the determination of branched-chain amino acids in dietary supplements

This study presents a low-cost, accessible TLC-UV/Vis spectrophotometric method for screening the total content and relative proportions of branched-chain amino acids in dietary supplements, offering a viable alternative for routine quality control despite its inability to fully replace reference chromatographic techniques.

Malco Bracco¹, Abril María Espinosa¹, Federico Martín Portilla¹, Pablo Raúl Castello¹2026-07-14✓ Author reviewed
📄 chemistry

Novel Pt,Ru-Codoped In₂S₃/Ta₂O₅ heterostructured films for the effective enhancement of visible-light photocatalytic degradation of rhodamine B

This study demonstrates that Pt,Ru-codoped In₂S₃/Ta₂O₅ heterostructured films, optimized with 75 wt.% In₂S₃ and fabricated via hydrothermal and doctor blading methods, achieve 92.0% visible-light degradation of Rhodamine B within 120 minutes by leveraging narrow bandgap absorption, oxygen vacancies, and strong electronic interactions to enhance charge separation and superoxide radical generation.

Natkritta Boonprakob, Natthakit Huatong, Narong Chanlek, Kemawadee Udonpan, Chaiyuth Sae-Kung, Chen Zhao2026-07-14
📄 chemistry

Application of Different Drying Techniques on the Chemical Composition and Antimicrobial Activities of the lemon verbena (Lippia Citrioodora Kunth palau) Essential Oil

This study demonstrates that microwave drying at 300W yields lemon verbena essential oil with the highest concentration of secondary metabolites and diverse bioactive compounds, while oven drying at 30°C produces the strongest antimicrobial activity against *Streptococcus pyogenes*, highlighting the significant influence of drying techniques on the oil's chemical profile and pharmaceutical potential.

Saemeh Rahdari, Maryam Rahimi, Zeynab Mohkami, Ali Ghorbani Ranjbari, Dariush Ramezan2026-07-14
📄 chemistry

Surrogate-Free Inverse Design of High-IP/High-EA Polyimide Constitutional Repeating Units with In-Loop Semiempirical Quantum Scoring

This study presents a surrogate-free inverse-design workflow combining recurrent-neural-network-guided Monte Carlo Tree Search with in-loop GFN2-xTB scoring to successfully generate a library of polyimide constitutional repeating units that simultaneously achieve deep ionization potentials and large electron affinities, overcoming the typical trade-off between these properties.

Yingda Li, Rong Sun, Jibao Lu2026-07-14
📄 chemistry

Preparation of tetra-branched PEG network and its application to gel polymer electrolyte

This paper reports the synthesis of a gel polymer electrolyte with a tetra-branched network structure via a thiol-yne click reaction, demonstrating that its ionic conductivity is influenced by polymer content and PEG chain length, which facilitates lithium cation transport along the polymer chains in addition to the electrolyte solution.

Tomoya Enoki, Ryodai Kagami, Takahiro Uno, Nanami Sasaki, Nobuyuki Imanishi, Masataka Kubo2026-07-14