Metastable states of 2D-material-on-metal-islands structures revealed by thermal cycling
This study reveals that thermal cycling induces irreversible degradation in the van der Waals bonding and electronic transport of hBN/graphene heterostructures on metallic islands due to thermal-expansion-driven delamination and interfacial residue redistribution, while demonstrating that hot pressing can restore contact and highlighting the critical role of interfacial stability in 2D device applications.