Pressure-induced lattice instabilities and phonon softening in the orthorhombically distorted ferrimagnet Ni4Nb2O9
This study utilizes NMR, Raman spectroscopy, and synchrotron XRD to demonstrate that the orthorhombically distorted ferrimagnet Ni4Nb2O9, despite sharing a local structural environment with its trigonal analogue Mn4Nb2O9, exhibits distinct average symmetry and undergoes pressure-induced lattice instabilities and phonon softening that drive a sequence of isostructural transitions culminating in a symmetry-lowering transformation to a monoclinic phase around 13 GPa.