Effect of hybrid field coupling in nanostructured surfaces on anisotropic signal detection in nanoscale infrared spectroscopic imaging methods
This study investigates how hybrid field coupling between IR illumination, nanostructured surfaces, and metallic probes induces anisotropic signal distributions in nanoscale infrared spectroscopy, utilizing quantum chemical calculations and PiF-IR imaging of aligned perylene monolayers to distinguish these electromagnetic effects from molecular orientation contributions.