Stabilization of a non-superconducting, orthorhombic phase by over-hydrogenating LaFeSiH
This study demonstrates that high-pressure thermal decomposition of hydrogen-rich precursors enables the over-hydrogenation of LaFeSi to stabilize a new, orthorhombic, semiconductor-like LaFeSiH phase, which can subsequently be tuned back to a superconducting state through controlled hydrogen release.