Investigating Roles of Triple Excitations for High-precision Determination of Clock Properties of Alkaline Earth Metal Singly Charged Ions
This study employs relativistic coupled-cluster theory to demonstrate the critical importance of triple excitations in accurately determining the electric dipole polarizabilities and quadrupole moments of clock states in singly charged alkaline-earth metal ions (Ca, Sr, and Ba), while also deriving nuclear quadrupole moments that reveal significant deviations from existing literature values.