📄 chemistry

Evolution of microstructure and mechanical properties of EB-PVD GZO/GYbZ/8YSZ multilayer thermal barrier coatings during thermal cycling

This study investigates the microstructural evolution and mechanical property changes of novel EB-PVD GZO/GYbZ/8YSZ multilayer thermal barrier coatings during thermal cycling, revealing that while the coating maintains integrity up to 100 cycles with sintering-induced property improvements, it suffers from severe delamination and reduced fracture toughness after 200 cycles due to surface cracking and interfacial oxidation.

weiguo mao, xiaojiao zhou, yongguo chen, le wang, kaixuan li, guangfang Chi, wenzhuo dai, xizhi fan, xing Tang, wenting (…)2026-06-25
📄 chemistry

Post-polymerization synthesis of a poly(α-naphthylamine)/ninhydrin composite with enhanced surface area for efficient urea adsorption

This study reports the successful synthesis of a novel poly(α-naphthylamine)/ninhydrin composite via post-polymerization modification, which features an enhanced porous surface area and covalent Schiff base linkages to achieve efficient, stable, and reusable urea adsorption from aqueous environments.

Esmail Mohseni, Babak Babaee, Mohammad sina Sheikh ali khani, Armita Khazaii2026-06-25
📄 chemistry

Novel Benzo[b][1,5] naphthyridine–Arylhydrazone Hybrids as EGFR-Targeted Anticancer Agents: Synthesis, DFT, and MCF-7 Antiproliferative Evaluation

This study reports the synthesis, characterization, and biological evaluation of novel benzo[b][1,5]naphthyridine–arylhydrazone hybrids, identifying compound **3a** as a potent EGFR-targeted anticancer agent against MCF-7 breast cancer cells through integrated experimental assays, molecular docking, and DFT calculations.

Jay B. Maheta, Darshna K. Lakhnotra, Yogesh O. Bhola2026-06-25
📄 chemistry

Two-electron mediation enables fast alkali peroxide cycling and suppresses side reactions in metal-O2 cells

This paper demonstrates that employing two-electron mediators in aprotic alkali metal–O2 batteries enables direct control over the second electron transfer to form peroxides, thereby suppressing the degradation-causing disproportionation of superoxide intermediates and transforming the reaction mechanism from a difficult-to-control chemical-electrochemical process into a fully mediated electrochemical one.

Stefan Freunberger, Lu He, Shuo Wang, Xin Xu, Soumyadip Mondal, Hongrui He, Rajesh Jethwa, Wentao Wang, Kun Wang, Jie Zh (…)2026-06-25
📄 chemistry

Effect of Calcination Temperature on the Synthesis of Silicon Carbide from Rice Husk with Copper Additive

This study demonstrates that adding copper as a catalyst enables the efficient synthesis of high-purity silicon carbide from rice husk at significantly reduced temperatures (900–1300°C) via a Vapor–Liquid–Solid mechanism, achieving an 88.47% yield at 1300°C compared to traditional non-catalytic methods requiring temperatures above 1500°C.

Do Trung Kien Kieu, Ngoc Minh Huynh, Vu Uyen Nhi Nguyen, Le My Duyen Tran2026-06-24
📄 chemistry

Real-time Multi-instrument Autonomous Materials Screening for Discovery of Novel Phase-change Memory Materials

This paper introduces the Multi-instrument Autonomous Discovery (MAD) framework, which integrates heterogeneous data from X-ray diffraction and electrical resistance measurements via a co-regionalized multi-output model to simultaneously optimize structural mapping and functional properties, thereby accelerating the discovery of novel Mn-Sb-Te phase-change memory materials by seven-fold through a closed-loop autonomous process.

Ichiro Takeuchi, Chih-Yu Lee, Haotong Liang, Ryan Kim, Carlos Ríos Ocampo, Austin McDannald, A. Gilad Kusne2026-06-24
📄 chemistry

Thin layer chromatographic detection of chlorpyrifos in human biological fluids using low-cost chromogenic reagent

This study developed a simple, rapid, and low-cost thin-layer chromatography method using a copper sulphate chromogenic reagent for the selective qualitative and semi-quantitative detection of chlorpyrifos in human blood and gastric aspirate, offering a reliable screening tool for poisoning cases in resource-limited settings.

Suraj D. Kukade, J. B. Tirpude, B. H. Tirpude, P. N. Murkey2026-06-24
📄 chemistry

AQbD-Assisted Development and Validation of a Green RP-HPLC Method for Simultaneous Quantification of Telmisartan, Amlodipine Besylate, and Bisoprolol Fumarate

This study presents a robust, accurate, and environmentally sustainable RP-HPLC method for the simultaneous quantification of Telmisartan, Amlodipine, and Bisoprolol, developed and optimized using an Analytical Quality by Design (AQbD) approach to ensure reliability for routine pharmaceutical quality control.

Paresh Ghughuskar, Ratna Musale, HIRALBEN MEHTA, Prexa Tandel2026-06-24