📄 chemistry

Chicken Feather-Derived Keratin-Based Bioplastic as a Corrosion Inhibitor for Mild Steel in 0.1 M HCl: Electrochemical, Gravimetric and Adsorption Studies

This study demonstrates that a keratin-based bioplastic derived from waste chicken feathers effectively inhibits mild steel corrosion in 0.1 M HCl through concentration- and temperature-dependent adsorption, achieving a maximum efficiency of 54% at 323 K while functioning as a mixed-type inhibitor.

Taiwo Omowumi Alonge, Ezekiel Adewole, Oluwafemi Temitayo Ogunmodede, Abiodun Ayodele Ojo, Funmilayo Deborah Adewumi, Ol (…)2026-10-05
📄 chemistry

Dynamic amorphous confinement stabilizes crystalline IrO2 for ultra-durable proton exchange membrane water electrolysis

This study presents a dynamically stabilized crystalline–amorphous hybrid IrO₂ catalyst that overcomes the traditional activity–stability trade-off in acidic water electrolysis by confining conductive crystalline nanodomains within a porous amorphous matrix, thereby enabling ultra-durable operation with high current densities and negligible degradation over 3400 hours.

Xinlong Tian, p pangbingqian, Yun Liu, Yixiang He, Zhenye Kang, Hui Chen, Shuyu Zhang, Jing Li, Yuliang Yuan, Peng Rao (…)2026-10-05
📄 chemistry

Sc/Zr and Zn/Zr modification of Al–7Mg alloys fabricated by laser- directed energy deposition: Grain refinement, tensile properties, and corrosion behavior

This study demonstrates that optimizing Sc/Zr and Zn/Zr modifications in laser-directed energy deposited Al–7Mg alloys effectively refines grain structure to achieve a superior balance of high tensile strength and corrosion resistance, offering a cost-effective strategy for reducing reliance on scandium.

Umar Daraz, Hyunkyu Lim, Bong-Hwan Kim, Abdul Wahid Shah, Shae K. Kim2026-10-05
📄 chemistry

Substituent Effects on Electronic Properties and Acetylcholinesterase Inhibitory Potential of Donepezil Analogues: A DFT, Molecular Docking, and ADMET Study with Dynamics Validation of the Lead Candidate

This study employs a comprehensive computational approach, including DFT, molecular docking, and dynamics simulations, to identify the donepezil derivative MH-4 as a promising, stable, and safe acetylcholinesterase inhibitor with enhanced electronic properties and favorable pharmacokinetics for Alzheimer's disease treatment.

Muhammad Mohsin Ejaz, Hamza Iftikhar, K.S. Al-Namshah, Saira Khan, Sadaf Ashraf, Nazia Meer, Musarat Riaz, Muhammad Sale (…)2026-10-05
📄 chemistry

Trans-A2B2 type meso-5-Nitrothien-2-yl Porphyrins: Scalable Synthesis, Spectroscopic and Physicochemical Investigations

This paper reports the scalable two-step synthesis of trans-A2B2 meso-5-nitrothien-2-yl porphyrins and demonstrates through spectroscopic and electrochemical analyses that the near-coplanar thienyl substituents induce strong electronic communication with the porphyrin core, evidenced by anodic redox shifts and bathochromic absorption changes.

C. Arunamaheswari, P. Gayathri, P. Bhavana, J. Veerarajan, R. Prasath2026-10-05
📄 chemistry

Coupling anisotropic site substitutions in Sr7-xAxMn4O15, A = Ca and Ba to acoustic instabilities and lattice distortions

This study reveals that the complex lattice distortions in Sr7-xAxMn4O15 (A = Ca, Ba) arise from the coupling between anisotropic site substitutions and acoustic instabilities mediated by rigid unit modes, offering a new framework for understanding how chemical disorder drives structural responses in functional materials.

Mark Senn, Struan Simpson, Gabriel Clarke, Clemens Ritter, Nicholas Funnell, Bora Karasulu2026-10-05
📄 chemistry

Carryover of neotame, WS-23, and other additives from popular disposable e-cigarettes to aerosol

This study analyzed 17 popular disposable e-cigarettes and found that while sweeteners like neotame and coolants like WS-23 are present in the e-liquids, a significant portion (ranging from 26% to 88%) of these compounds, along with nicotine and menthol, is carried over into the inhaled aerosol, highlighting substantial user exposure to these additives.

Remi A. Mellinghoff, Isabel X. Maday, Elena M. Bouldin, Paul T. Anastas, Stephanie S. O'Malley, Suchitra Krishnan-Sarin (…)2026-10-05
📄 chemistry

Microbial Synthesis of Reduced Graphene Oxide Nanosheets by Proteus mirabilis MT378377 and Antibacterial Activity against Multidrug Resistant Bacteria

This study reports the optimized microbial synthesis of reduced graphene oxide nanosheets using *Proteus mirabilis* MT378377 under specific conditions of temperature, pH, and additives, revealing that while the resulting nanomaterials possess suitable characteristics for drug delivery, they exhibit lower antibacterial activity against multidrug-resistant bacteria compared to graphene oxide.

Mehwish Iqtedar, Sana Rashid, Mahwish Aftab, Afshan Kaleem, Roheena Abdullah2026-10-01
📄 chemistry

Synergistic dual-modification of polyurethane sponge with MIL-53(Al) and dimethylsilicone oil for efficient oil–water separation of oily sludge thermal washing wastewater

This study presents a synergistically dual-modified polyurethane sponge (M/Si-6@PU) coated with MIL-53(Al) and dimethylsilicone oil that achieves superhydrophobicity, rapid oil absorption, and exceptional cyclic stability for the efficient separation of oily sludge thermal washing wastewater.

Junjie Pan, Chunyu Wang, Xiaoting Hong, Xuegang Zhang, Huanyang Liu, Junye Guo, Yanghao Huang, Chengyue Wang2026-10-01