1656 papers
This study reports the synthesis of a stable, broad-spectrum S-scheme CuFe2O4/CuO/C heterojunction derived from Prussian blue analogues that efficiently degrades tetracycline antibiotics under visible light via a mechanism dominated by superoxide radicals and photogenerated holes.
This study reports the synthesis and characterization of a novel family of air-stable, diabolo-shaped nonanuclear lanthanide (Tb, Dy, Ho, Er) clusters bridged by hydroxide/oxide and 1-phenyl-1,3-butanedione ligands, demonstrating that their specific topology facilitates antiferromagnetic exchange interactions that suppress quantum tunneling and enhance single-molecule magnet performance, as confirmed by both experimental magnetic measurements and advanced ab initio theoretical calculations.
This study demonstrates that ultrafiltration serves as an effective diagnostic and concentration tool for identifying and recovering hidden, fine-dispersed uranium losses in production mother liquors without chemical additives, thereby enabling detailed characterization of uranium-bearing particles and minimizing overall process losses.
This study demonstrates that a sulfonated dolomite iron (SDI) catalyst, synthesized from waste iron filings and dolomite, outperforms a sulfonated calcined iron (SCI) catalyst in converting cow tallow to biodiesel via transesterification, achieving a 77.995% yield attributed to its superior surface area, pore volume, and sulfate-rich phase composition.
This paper reports a mild, silver-catalyzed radical cascade cyclization of α-imino-oxy acids with α-trifluoromethyl acrylamides to efficiently synthesize cyanoalkyl-substituted 3-trifluoromethyl-2-oxindoles with broad substrate scope and utility in late-stage functionalization.
This study demonstrates that a K-promoted Ni/MgO nanosheet catalyst achieves highly selective CO production via a carbonate-bicarbonate mediated pathway at 350°C, effectively suppressing methanation and outperforming most noble-metal catalysts for low-temperature CO2 hydrogenation.
This study overcomes the reductive dimerization bottleneck in PFAS degradation by employing an asymmetric advanced oxidation process that utilizes vacuum ultraviolet irradiation to intercept ultra-short intermediates via localized orbital polarization, thereby enabling complete defluorination through a synergistic oxidant-to-reductant ratio defined by a newly established chemical descriptor.
This study demonstrates that fir sawdust is an effective biosorbent for removing uranium from wastewater via chemical adsorption and ion exchange mechanisms, achieving optimal removal at pH 4.5 with a maximum monolayer capacity of 148.81 mg g⁻¹.
This paper introduces and rigorously validates a closed-form, first-principles physics model for predicting key atomic properties, achieving a mean absolute percentage error of 0.17% across 56 NIST reference indicators while providing comprehensive documentation, comparative analysis, and links to sustainable development goals.
This study demonstrates that a pilot-scale steam explosion pretreatment of sugarcane straw, optimized with a specific combination of higher soaking pH and sodium metabisulfite addition, effectively mitigates pseudo-lignin formation to achieve 100% enzyme accessibility and maximum hydrolysis yields at low enzyme dosages.