1045 papers
This paper reports a novel polymerization strategy that utilizes a hydrogen atom-coupled electron transfer (HCET) process to bridge radical and anionic mechanisms, enabling the synthesis of diverse polymers under aerobic conditions with Earth-abundant reagents and unpurified chemicals.
This study demonstrates that human myeloperoxidase (MPO), released by neutrophils during skin sensitization, enzymatically oxidizes specific aromatic diamines and phenylpropanoids into protein-reactive metabolites, thereby revealing a previously unrecognized biological activation pathway that complements existing abiotic and epidermal metabolic mechanisms.
This study reports the synthesis of erbium-intercalated V₂C MXene, a sunlight-responsive nanoplatform that effectively degrades sulfamethoxazole and Rhodamine B while exhibiting selective cytotoxicity against HeLa cancer cells, demonstrating the potential of rare-earth intercalation to engineer multifunctional MXenes for integrated environmental and biomedical applications.
This study demonstrates that phosphorus doping effectively enhances the electrical conductivity and structural stability of zinc oxide nanostructures, with one-dimensional rod-like morphologies (ZNR-P2) exhibiting superior supercapacitive performance, including a high specific capacitance of 513 F·g⁻¹ and a maximum energy density of 15.9 Wh·kg⁻¹ in an asymmetric device.
This study demonstrates that cellulose pulp with high yield (up to 40%) and suitable morphological properties for industrial applications can be successfully produced from the mid-rib wastes of four different *Musa paradisiaca* banana species in Nigeria via alkaline sulphite pulping, offering a sustainable alternative to wood-based raw materials.
This study presents a dynamic neosurface engineering strategy using a supramolecular peptide platform to chemically remodel the intrinsically disordered surface of aldose reductase (ALR2), creating a selective "NeoFunnel Interface" that enables high-affinity targeting and adaptive drug release while avoiding cross-reactivity with its homologous enzyme ALR1.
This study demonstrates that fabricating nickel-based composites reinforced with in-situ synthesized three-dimensional graphene-like networks via rapid thermal annealing and spark plasma sintering significantly enhances mechanical properties, achieving a 33.53% increase in yield strength and a 54.93% increase in ultimate tensile strength compared to pure nickel.
Two new three-dimensional cadmium coordination polymers were successfully synthesized via one-pot solvothermal reaction using a semirigid tripodal carboxylic acid and a flexible N-donor ligand, where the distinct trans and cis conformational configurations of the ligand dictate the formation of meso-helical chains and discrete ring structures, respectively.
This paper introduces Holistic History-aware Text (HHT), a framework that leverages natural language descriptions of polymer composition, synthesis, and processing via large language models to outperform traditional structure-only encoders in predicting macroscopic properties from heterogeneous literature-derived records.
This study presents a sustainable, continuous 30-day electrosynthesis of hydroxylamine from nitrate using a self-regenerative catalyst system that employs a reversible Bi³⁺/Bi redox cycle to dynamically repair catalyst aging and maintain high selectivity and current density.