Water, vacancies, and competing exchange interactions in Prussian blue analogues: a neutron diffraction study of field and dehydration-driven magnetic transitions
This neutron diffraction study elucidates how correlated vacancies and interstitial water govern the structural stability and magnetic transitions in Prussian blue analogues, revealing that dehydration or moderate magnetic fields can drive a spin reorientation in MnFe from a frustrated state to a collinear ferrimagnetic order by balancing competing exchange interactions.