📄 chemistry

Nanoscale Defect Modulation in Zn 1-x Ni x Fe 2 O 4 Spinel Nanoparticles: Hydrodynamic Agglomeration, Mesoporosity, and Coupled Magnetic and Electrochemical Responses

This study demonstrates that low-concentration nickel doping (specifically at x = 0.03) in ZnNiFe2O4 spinel nanoparticles induces a critical defect-rich mesoporous structure that simultaneously maximizes grain-boundary scattering to enhance magnetic coercivity and optimizes electrochemical charge storage, establishing a narrow compositional threshold for co-tuning multifunctional properties.

I. Dominic Xavier, R. Sagayaraj, A. Maria Bernadette Leena, N. Lavanya, C. Yogambal, A. Amalorpavadoss, S. Sebastian, S. (…)2026-08-31
📄 chemistry

Decoding the Behavior of Bio-Relevant Metal Ions in Water Using Chemometric Speciation Modeling

This study utilizes chemometric speciation modeling and pH-metric titrations to investigate the solution equilibria and stability of ternary nickel(II) and copper(II) complexes formed with azelaic acid dihydrazide and L-proline, providing insights into their potential applications in health, water purification, and green catalysis aligned with Sustainable Development Goals.

Nirmala Devi Danabala, Uma Rani Bhagavatula, Shyamala Pulipaka, Satyanarayana A, R S S Srikanth Vemuri, Chandra Sekhar B (…)2026-08-31
📄 chemistry

Mechanical and abrasion behaviour of cement and alkali-activated material mixes based on oil refinery waste catalyst: investigation and semi-empirical predictive models

This study demonstrates that incorporating 20 wt% oil refinery waste catalyst (ECAT) into cement mortars significantly enhances mechanical strength and abrasion resistance, while developing accurate semi-empirical predictive models for both cement and alkali-activated material mixes to support sustainable construction practices.

Natalia Szemiot-Jankowska, Masoumeh Khamehchi, Murugan Muthu, Shriram Marathe, Kamil Krzywiński, Lukasz Sadowski, Tianyu (…)2026-08-31
📄 chemistry

Phenol Adsorption from Water Using Raw and Quaternized Waste Sorbents: Isotherm, Kinetic, and Thermodynamic Analysis

This study demonstrates that quaternized agricultural waste peels from *Cucumis metuliferus* and *Aframomum melegueta* serve as highly effective, regenerable, and sustainable biosorbents for removing phenol from wastewater, achieving up to 95.95% removal efficiency through chemisorption mechanisms that outperform their raw counterparts.

James Ndiritu, John Wamumwe Mwangi2026-08-31
📄 chemistry

Literature Derived Polypropylene Mechanical Property Data for an Automotive Material Development Case Study Using a Quality Controlled Open Access Extraction Framework

This paper presents a quality-controlled, AI-assisted framework for extracting traceable mechanical property data from open-access scientific literature, demonstrating its application in a polypropylene case study where the system successfully generated candidate records while highlighting the challenges of reconstructing complete formulation-property relations compared to simple document retrieval.

Gabor BOCZ, Gabor DOGOSSY2026-08-31
📄 chemistry

Exposure-Integrated Risk Prioritization of Legacy and Emerging PFAS: A Case Study of a Major River Basin in South Korea via High-Resolution Mass Spectrometry

This study pioneers an exposure-integrated risk prioritization framework for the Geum River basin in South Korea by combining high-resolution mass spectrometry with QSAR-based hazard assessment, revealing that while long-chain PFAS possess the highest intrinsic toxicity, short-chain variants like PFBS and PFHxA along with PFOA constitute the greatest management priority due to their widespread environmental loading.

Minsu Shin, Gyojin Choo2026-08-31
📄 chemistry

Synthesis of a superabsorbent with low residual monomer content by gamma irradiation and improving gel strength through surface treatment

This study demonstrates that gamma irradiation can efficiently synthesize acrylic acid superabsorbents with negligible residual monomers, while subsequent surface cross-linking with DEGDGE significantly enhances gel strength and absorption under load, making the material ideal for hygiene and biomedical applications.

Azam Akhavan, Farahnaz Nasiri, Vagihe Nikfarjam, Payman Rezaeian, Mohamad reza Dadfar2026-08-31
📄 chemistry

A Two-Dimensional Crystal of Strongly Interacting Superatoms

This study demonstrates the formation of a strongly interacting two-dimensional crystal composed of covalently bonded Pd<sub>6</sub>Se<sub>20/21</sub> superatoms, which exhibit atomic-like electronic properties and crystalline defects, offering a unique model system for studying the nucleation and growth of atomic solids.

Gerd Duscher, Austin Houston, Wolfgang Windl, Sumner Harris, Daniel Yimam, Ivan Vlassiouk, David Geohegan, Kai Xiao2026-08-31
📄 chemistry

Ferrous-Assisted Corona Plasma Decolorization of Acid Black 194 and Auramine O in a Continuous-Flow Recirculation System

This study demonstrates that an atmospheric-pressure corona plasma system assisted by ferrous species in a continuous-flow recirculation setup effectively achieves over 97% decolorization of both the azo dye Acid Black 194 and the triarylmethane dye Auramine O within 90 minutes, with specific energy consumptions of approximately 40–42 kWh m⁻³.

Erik Torres, Aarón Gómez, Pedro Guillermo Reyes, José Carlos Palomares, Joséfina Vergara, César Torres, Horacio Martínez2026-08-31